Reactions of carboxylic acids

IMPORTANT

Reactions of carboxylic acids: Overview

This topic covers concepts, such as, Chemical Properties of Carboxylic Acids,Reactions of Carboxylic Acids involving Cleavage of O-H Bond,Acidity of Carboxylic Acids etc.

Important Questions on Reactions of carboxylic acids

MEDIUM
IMPORTANT

The correct increasing order of acidic strength of the following compounds is

(i) benzoic acid

(ii) 4-nitro benzoic acid

(iii)  3, 4-dinitrobenzoic acid

(iv) 4-methoxybenzoic acid

HARD
IMPORTANT

Identify A to D in the following sequences of operations:

 CH3CH2COOHΔNH3ABr2/KOH  BHONOC[O]CH3COOHDistilCa(OH)2D

EASY
IMPORTANT

Among the following acids which has the lowest  pKa value?

MEDIUM
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A liquid was mixed with ethanol and a drop of concentrated H2SO4 was added. A compound with a fruity smell was formed. The liquid was:

EASY
IMPORTANT

Which amongst the following compounds has the highest acid strength?

HARD
IMPORTANT

CH3COOH+SOCl2Products.

What are the products formed ?

MEDIUM
IMPORTANT

Complete the following reaction.

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MEDIUM
IMPORTANT

Nitration of benzoic acid occurs at the meta position. Give reason.

EASY
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Nitration of benzoic acid gives p-nitrobenzene.

MEDIUM
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Nitration of benzoic acid gives

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IMPORTANT

Write the conversion of benzoic acid into nitrobenzoic acid.

MEDIUM
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The following transformation

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can be carried out in three steps. The reagents required for these three steps in their correct order, are:

HARD
IMPORTANT

In the equation CH3COOH + Cl2 - HClRed Phosphorus A, the compound A is :

HARD
IMPORTANT

The product obtained when acetic acid is treated with PCl3 is:

MEDIUM
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When benzoic acid reacts with ammonia, product we get is _____.

MEDIUM
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During esterification reaction an alcohol and a _____ acid react with each other in the presence of acid to give esters.

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CH3COOHCH3COOCOCH3+H2O

In the above reaction, the number of moles of acetic acid required to prepare acetic anhydride is:

MEDIUM
IMPORTANT

The correct increasing order of acidities is:
ClCH2COOH1, Cl2CHCOOH2, Cl3CCOOH3